Figure 1. Sandwich making can illustrate the concepts of limiting and excess reactants. If these reactants are provided in any other amounts, one of the reactants will nearly always be entirely consumed, thus limiting the amount of product that may...
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Hydrogen, therefore, is present in excess, and chlorine is the limiting reactant. Reaction of all the provided chlorine 2 mol will consume 2 mol of the 3 mol of hydrogen provided, leaving 1 mol of hydrogen unreacted. An alternative approach to...
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View this interactive simulation illustrating the concepts of limiting and excess reactants. Example 1 Identifying the Limiting Reactant Silicon nitride is a very hard, high-temperature-resistant ceramic used as a component of turbine blades in jet engines. Solution Compute the provided molar amounts of reactants, and then compare these amounts to the balanced equation to identify the limiting reactant. Alternatively, compute the amount of product expected for complete reaction of each of the provided reactants. The 0. Check Your Learning Which is the limiting reactant when 5. Answer: O2 Percent Yield The amount of product that may be produced by a reaction under specified conditions, as calculated per the stoichiometry of an appropriate balanced chemical equation, is called the theoretical yield of the reaction.
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In practice, the amount of product obtained is called the actual yield, and it is often less than the theoretical yield for a number of reasons. Some reactions are inherently inefficient, being accompanied by side reactions that generate other products. Others are, by nature, incomplete consider the partial reactions of weak acids and bases discussed earlier in this chapter. Some products are difficult to collect without some loss, and so less than perfect recovery will reduce the actual yield.
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As long as both yields are expressed using the same units, these units will cancel when percent yield is calculated. Example 2 Calculation of Percent Yield Upon reaction of 1. Solution The provided information identifies copper sulfate as the limiting reactant, and so the theoretical yield is found by the approach illustrated in the previous module, as shown here: [latex]1. One of the 12 principles is aimed specifically at maximizing the efficiency of processes for synthesizing chemical products. The percent yield of a given chemical process, on the other hand, evaluates the efficiency of a process by comparing the yield of product actually obtained to the maximum yield predicted by stoichiometry.
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The synthesis of the common nonprescription pain medication, ibuprofen, nicely illustrates the success of a green chemistry approach Figure 3. The BHC process generates significantly less chemical waste; uses less-hazardous and recyclable materials; and provides significant cost-savings to the manufacturer and, subsequently, the consumer. Figure 3. The amount of product generated by a chemical reaction is its actual yield. This yield is often less than the amount of product predicted by the stoichiometry of the balanced chemical equation representing the reaction its theoretical yield.
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The extent to which a reaction generates the theoretical amount of product is expressed as its percent yield. What is the limiting reactant in a reaction that produces sodium chloride from 8 g of sodium and 8 g of diatomic chlorine? A student isolated 25 g of a compound following a procedure that would theoretically yield 81 g. What was his percent yield? A sample of 0. What is the percent yield for this reaction? The other product of this reaction is HCl. Outline the steps needed to determine the percent yield of a reaction that produces Freon has been banned and is no longer used as a refrigerant because it catalyzes the decomposition of ozone and has a very long lifetime in the atmosphere.
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Determine the percent yield. Citric acid, C6H8O7, a component of jams, jellies, and fruity soft drinks, is prepared industrially via fermentation of sucrose by the mold Aspergillus niger. What is the percent yield of a reaction that converts 1. Determine the theoretical yield in grams and the percent yield for this reaction. Outline the steps needed to solve the following problem, then do the calculations. Ether, C2H5 2O, which was originally used as an anesthetic but has been replaced by safer and more effective medications, is prepared by the reaction of ethanol with sulfuric acid.
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Outline the steps needed to determine the limiting reactant when Determine the limiting reactant. Outline the steps needed to determine the limiting reactant when 0. What is the limiting reactant when 1. Addition of 0. How many molecules of the sweetener saccharin can be prepared from 30 C atoms, 25 H atoms, 12 O atoms, 8 S atoms, and 14 N atoms? The phosphorus pentoxide used to produce phosphoric acid for cola soft drinks is prepared by burning phosphorus in oxygen.
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Explain why or why not. The limiting reactant is Cl2. Convert mass of ethanol to moles of ethanol; relate the moles of ethanol to the moles of ether produced using the stoichiometry of the balanced equation. Convert moles of ether to grams; divide the actual grams of ether determined through the density by the theoretical mass to determine the percent yield; Then compare the amount of Cr to the amount of acid present.
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Easy Access Study Guide
Cr is the limiting reactant. Na2C2O4 is the limiting reactant. Only four molecules can be made. This amount cannot be weighted by ordinary balances and is worthless.
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The Solubility Of Ce(IO3)3 In A 0.20 M KIO3 Is 4.4 10-8 Mol/L. Calculate Ksp For Ce(IO3)3?
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